The "Mr and Mrs Smith" co-stars looked stunning on the red carpet with Jolie in a form flattering floor-length Ralph & Russo dress while Brad opted for the traditional black and white tuxedo.
Earlier in the day, Ms Jolie offered up some information about her plan to write a new piece about the conflict in Afghanistan.
"I did write something on Afghanistan. Nobody's seen it yet," she told and then added, "Brad hasn't seen it. It's hidden. So I don't know how very good it is, but it's been a pleasure to write."
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